Rodenticides
Speciality Products
Bednet Treatment
Fogging
IRS
Locust Control
PCO
Plant Nutrients
Plant Protection
Relevant identified uses of the substance or mixture and uses advised against
Details of the supplier of the safety data sheet.
Tagros Chemicals India Ltd.
“Jhaver Centre”, Rajah Annamalai Building,
IV Floor, 72, Marshalls Road,
Egmore, Chennai-600 008, India
Telephone number: +91-44-42007400
E-mail: info@tagros.com
Emergency telephone number
+91-44-28587873
info@tagros.com
POTENTIAL HEALTH EFFECTS: EMERGENCY OVERVIEW
Eyes
May cause eye irritation. Avoid contact with eyes.
Skin
Harmful if absorbed through skin. Do not get on skin or clothing.
Harmful if swallowed.
Inhalation
Harmful if inhaled. Avoid inhalation of vapour or mist.
Environment
Dangerous for the environment. Very toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment.
Substances.
Chemical name |
CAS No: |
EC No. |
Classification |
Con. % w/w |
Permethrin (ISO)3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
|
52645-53-1
|
258-067-9 |
Xn; R20/22
|
50.0
|
Others |
50.0
|
Immediately rinse eyes thoroughly, including under eyelids, with running water for at least 15 minutes. Seek immediate medical advice.
Contact with skin
Carefully remove contaminated clothing. Wash affected area with soap and water. Seek medical aid if required.
Ingestion
If the material was swallowed and signs of toxicity are severe, induce vomiting. Keep the person calm and comfortable and obtain medical assistance as soon as possible.
If inhaled, remove to fresh air and keep at rest. Obtain medical aid if required.
Flash point
Extinguishing media
If product is involved in a fire, use water spray, foam, dry powder, carbon dioxide or sand. Keep nearby containers and equipment cool with a water stream.
In the event of fire, hydrogen chloride, carbon monoxide and carbon dioxide may be released..
Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.
Personal precautions
Avoid contact with spilled material or contaminated surfaces. If ordinary clothing becomes contaminated remove it immediately. When dealing with the spillage do not eat, drink or smoke and wear personal protective clothing as detailed in section 8.
Environmental precautions
Keep people and animals away. Prevent entry into drains, sewers and watercourses.
Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.
Wear chemically impervious gloves such as neoprene or nitrile. Wear safety glasses, goggles or face shield. Mechanical ventilation should be used when handling this product in enclosed spaces. Read and observe all precautions and instructions on the label.
Store in original containers, upright and closed. Store in areas that are cool, dry and well ventilated. Store away from seeds, fertilizers and animal feed stuff.
ADI: 0.05 mg/kg bw (JMPR 1999)
Mechanical ventilation should be used when handling this product in closed spaces.
When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations.
Hand protection
Wear chemical resistant nitrile gloves.
Eye/face protection
Wear safety goggles with imperforated side shield and face shield.
Skin protection
Avoid contact with skin. Wear apron, boots and full protective suit.
Environmental exposure controls
Information on basic physical and chemical properties
Yellow
Odour
391.3 (Permethrin)
>45°C
Emulsify in water
Stable for two years at ambient conditions.
Conditions to avoid
Avoid excessive heat and flame.
Materials to avoid
None under normal condition of use.
Oxidizing & alkaline materials.
Acute toxicity
>2000 mg/kg bw (Permethrin)
>2000 mg/kg bw (Permethrin)
Slight-irritant to skin of rabbits (Permethrin)
Minimally irritating to eye of rabbits (Permethrin)
Harmful if swallowed.
Harmful if inhaled. Avoid inhalation of vapour or mist.
Carcinogenicity
Non carcinogenic in rats
Mutagenicity
Non mutagenic
Reproductive toxicity
Non reprotoxic and teratogenic
EcoToxicity
Guppy, Poecilia reticulata, 96 hours
LC50 : 8.9 µg/l (Permethrin)
LC50 : 0.145 mg/l (Permethrin)
EC50: >0.022 mg/l (Permethrin)
EC50:>1000mg/l (Permethrin)
Strongly adsorbed in soil particles with no risk of leaching.
Very toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment. DT50 pH 4 at 25ºC: > 1 year (water).
Do not empty into drains or waterways. Disposal of product would usually be by incineration in an appropriate licensed commercial incinerator. Advice may be obtained from local waste regulation authorities.
Puncture container to avoid re-use. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by local authorities, by burning. If burned, stay out of smoke. Follow advice on product label and/or leaflet.
UN number
UN Class
6.1
Proper Shipping Name
PYRETHROID PESTICIDE LIQUID, TOXIC, FLAMMABLE N.O.S
Xn: Harmful
N: Dangerous for the environment
Risk Phrases
R10: Flammable
R20/22: Harmful by inhalation and if swallowed.
S2: Keep out of the reach of children.
S13: Keep away from food, drink and animal feed stuffs
S24/24: Avoid contact with skin and eyes.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S60: This material and its container must be disposed off as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions/safety data sheets.
Regulation (EC) No 1907/2006
18th June 2002
25th August 2011
The above information is intended to give general health and safety guidance on the storage and transport of the substance or product to which it relates. It is not intended to apply to the substance or product for which purposes the substance or product label and any appropriate technical usage literature available should be consulted and any relevant licenses, consents or approvals complied with. The requirement or recommendation of any relevant site or working procedure, system or policy in force or arising from any risk assessment involving the substance or product should take precedence over any of the guidance contained in this safety data sheet where there is a difference in the information given. The information provided in this safety data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted for any injury loss or damage resulting from any failure to take account of information or advice contained in this safety data sheet.